Molecules

Copper-Catalyzed Three-Five-or Seven-Component Coupling Reactions: The Selective Synthesis of Cyanomethylamines, N, N-Bis (Cyanomethyl) Amines …

N Sakai, N Takahashi, D Inoda, R Ikeda, T Konakahara

文献索引：Sakai, Norio; Takahashi, Nobuaki; Inoda, Daiki; Ikeda, Reiko; Konakahara, Takeo Molecules, 2013 , vol. 18, # 10 p. 12488 - 12499

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被引用次数: 2

摘要

Abstract: We have demonstrated that a cooperative catalytic system comprised of CuCl and Cu (OTf) 2 could be used to effectively catalyse the three-, five-and seven-component coupling reactions of aliphatic or aromatic amines, formaldehyde, and trimethylsilyl cyanide (TMSCN), and selectively produce in good yields the corresponding cyanomethylamines, N, N-bis (cyanomethyl) amines and N, N'-bis (cyanomethyl) methylenediamines.