New approach to phosphinoalkynes based on Pd-and Ni-catalyzed cross-coupling of terminal alkynes with chlorophosphanes

IP Beletskaya, VV Afanasiev, MA Kazankova…

文献索引：Beletskaya, Irina P.; Afanasiev, Vladimir V.; Kazankova, Marina A.; Efimova, Irina V. Organic Letters, 2003 , vol. 5, # 23 p. 4309 - 4311

全文：HTML全文

被引用次数: 57

摘要

The first example of direct phosphination of terminal alkynes with chlorophosphanes catalyzed by Ni or Pd complexes is described. Both aromatic and aliphatic terminal acetylenes undergo the coupling reaction to give corresponding coupling product in high yield.