Inorganic Chemistry

Thermal decomposition of energetic materials. 30. Thermolysis of energetic metal-nitraminato complexes under conditions that simulate combustion

SF Palopoli, TB Brill

文献索引：Palopoli, S. F.; Brill, T. B. Inorganic Chemistry, 1988 , vol. 27, p. 2971 - 2976

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被引用次数: 7

摘要

The thermal decomposition of six energetic nitraminato complexes of Cu (II), Pd (I1) and Ni (I1) was investigated at 5" C/min by IR spectroscopy and DSC and at 100" C/s (to simulate combustion) by rapid-scan infrared spectroscopy. The objective was to correlate, insofar as possible, the structure and bonding of the parent complex to the decomposition behavior and products. The metal-nitraminato complexes decompose very rapidly. The gases ...