Phosphorus-containing disiloxanes: Synthesis and thermal rearrangement of the 1, 2-shift type

…, TM Shcherbina, PV Petrovskii, EE Nifant'ev

文献索引：Molchanova; Shcherbina; Petrovskii; Nifant'ev Russian Chemical Bulletin, 2005 , vol. 54, # 5 p. 1245 - 1249

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摘要

Abstract Methods for the synthesis of tetramethylbis (ω-phosphoryloxyalkyl) disiloxanes were developed. Thermal rearrangement of the 1, 2-shift type of tetramethylbis (phosphoryloxymethyl) disiloxanes was studied. The 1, 2-shift rearrangement of dimethyl ( diphenoxyphosphoryloxymethyl) silyl hydrogen sulfate was found.