A High-Valent Iron–Oxo Corrolazine Activates C–H Bonds via Hydrogen-Atom Transfer

…, P Leeladee, AJ McGown, S DeBeer…

文献索引：Cho, Kevin; Leeladee, Pannee; McGown, Amanda J.; Debeer, Serena; Goldberg, David P. Journal of the American Chemical Society, 2012 , vol. 134, # 17 p. 7392 - 7399

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被引用次数: 24

摘要

Oxidation of the FeIII complex (TBP8Cz) FeIII [TBP8Cz= octakis (4-tert-butylphenyl) corrolazinate] with O-atom transfer oxidants under a variety of conditions gives the reactive high-valent Fe (O) complex (TBP8Cz+•) FeIV (O)(2). The solution state structure of 2 was ...