Polyhedron

Probing the limits of steric constraints in the oligomerization of copper (I) complexes: structures of two sterically congested oligomers

C Wycliff, DS Bharathi, AG Samuelson, M Nethaji

文献索引：Wycliff, Christina; Bharathi, D. Saravana; Samuelson, Ashoka G.; Nethaji, Munirathinam Polyhedron, 1999 , vol. 18, # 7 p. 949 - 958

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被引用次数: 13

摘要

Oligomeric copper (I) clusters are formed by the insertion reaction of copper (I) aryloxides into heterocumulenes. The effect of varying the steric demands of the heterocumulene and the aryloxy group on the nuclearity of the oligomers formed has been probed. Reactions with copper (I) 2-methoxyphenoxide and copper (I) 2-methylphenoxide with PhNCS result in the formation of hexameric complexes hexakis [N-phenylimino (aryloxy) methanethiolato ...