Diels-Alder reactions of cycloalkenones. 20. Diels-Alder reactions of a bicyclic, cross-conjugated dienone

S Alunni, L Minuti, P Pasciuti, A Taticchi…

文献索引：Alunni, Sergio; Minuti, Lucio; Pasciuti, Patrizia; Taticchi, Aldo; Guo, Ming; Wenkert, Ernest Journal of Organic Chemistry, 1991 , vol. 56, # 18 p. 5353 - 5356

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被引用次数: 4

摘要

Aluminum chloride catalyzed Diels-Alder reactions of a bicyclic dienone of the 2, 5- cyclohexadienone type with l,% butadiene, isoprene, and (E)-piperylene are described. Structure analysis of the adducts by NMR spectroscopy is presented. The site selectivity and face diastereoselectivity of the reactions are discussed.