Nucleophilic aromatic substitution in microemulsions

…, CA Bunton, F De Buzzaccarini

文献索引：Athanassakis, Vassilios; Bunton, Clifford A.; Buzzaccarini, Francesco de Journal of Physical Chemistry, 1982 , vol. 86, # 25 p. 5002 - 5009

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被引用次数: 23

摘要

The rate constants of reaction of 2, 4-dinitrofluorobenzene (DNF) with OH-in microemulsions of n-octane, tert-amyl alcohol, and cetyltrimethylammonium bromide (CTABr) and in micelles of CTABr and tert-amyl alcohol can be treated quantitatively by using a pseudophase ion- exchange model and the second-order rate constants in the microemulsion or micelle droplets are larger than that in water, but much smaller than those in moist tertiary ...