Bulletin of the Chemical Society of Japan

Effect of Hyperconjugation on the Decomposition of N-Alkyl-N-nitrosoacetamide

M Murakami, K Akagi, Y Mori

文献索引：Murakami,M. et al. Bulletin of the Chemical Society of Japan, 1962 , vol. 35, p. 11 - 15

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被引用次数: 3

摘要

The effect of the β-phenyl group on the decomposition of N-sec-alkyl-N-nitrosoacetamide was found to be more pronounced when the alkyl group was cyclohexyl than when it was isopropyl, and the heat of activation of N-cyclohexyl-N-nitrosoacetamide was smaller than that of N-isopropyl-N-nitrosoacetamide. Hence the second order hyperconjugation was suggested as more probable for the cycloalkyl group. This hypothesis was supported by a ...