Copper??Catalyzed Trifluoromethylation of Internal Olefinic C H Bonds: Efficient Routes to Trifluoromethylated Tetrasubstituted Olefins and N??Heterocycles
Z Mao, F Huang, H Yu, J Chen, Z Yu…
文献索引：Yu, Haifeng; Yu, Zhengkun Angewandte Chemie, International Edition, 2009 , vol. 48, p. 2929 - 2933 Angewandte Chemie, 2009 , vol. 121, p. 2973 - 2977
Abstract The functionalization of internal olefins has been a challenging task in organic synthesis. Efficient Cu II-catalyzed trifluoromethylation of internal olefins, that is, α-oxoketene dithioacetals, has been achieved by using Cu (OH) 2 as a catalyst and TMSCF 3 as a
