Carbonates, Thiocarbonates, and the Corresponding Monoalkyl Derivatives. 1. Their Preparation and Isotropic 13C NMR Chemical Shifts

D Stueber, D Patterson, CL Mayne, AM Orendt…

文献索引：Stueber; Patterson; Mayne; Orendt; Grant; Parry Inorganic Chemistry, 2001 , vol. 40, # 8 p. 1902 - 1911

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被引用次数: 28

摘要

The potassium carbonate and thiocarbonate salts K2CO3-n S n (n= 0, 1, 2, 3) and the related monoalkyl derivatives KXYCZR (X, Y, Z= O, S; R= CH3, CH2CH3, CH (CH3) 2) were synthesized, in part following newly developed methods. The corresponding isotropic solid- state 13C and aqueous solution 13C and 1H chemical shift data were measured. Trends in the 13C chemical shift values are interpreted in terms of concepts on the structure ...