Electron and energy transfer between bicyclo [2.2. 2] octane bridgehead moieties

HE Zimmerman, RD McKelvey

文献索引：Zimmerman,H.E.; McKelvey,R.D. Journal of the American Chemical Society, 1971 , vol. 93, # 15 p. 3638 - 3645

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被引用次数: 42

摘要

Abstract: 1, 4-Diphenylbicyclo [2.2. 2] octane, 1, 4-bis (p-cyanophenyl) bicyclo [2.2. 2] octane, 1, 4-bis (p-nitrophenyl)-bicyclo [2.2. 2] octane, and l-benzoyl-4-(~ u-naphthyl) bicyclo [2.2. 2] octane were synthesized for energy and electrontransfer studies. Introduction of an odd electron into one aromatic ring of the symmetrical diary1 derivatives led to radical anions in which the odd electron was localized in one of the two rings. This result is ...