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Journal of the American Chemical Society

Optical Rotatory Dispersion Studies. XXIV. 1 Effect of Distance of a Single Asymmetric Center from an Aliphatic Carbonyl Function2

C Djerassi, LE Geller

文献索引:Djerassi; Geller Journal of the American Chemical Society, 1959 , vol. 81, p. 2789,2794

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被引用次数: 71

摘要

A series of optically active aliphatic aldehydes and methyl ketones has been synthesized for optical rotatory dispersion measurements. The single asymmetric center was always the same (S) since it was derived from (-)-2-methylbutanol-1 (“optically active amyl alcohol”) which has been related to L-glyceraldehyde. The series of methyl ketones consisted of members in which the carbonyl function was separated by 0, 1, 2, 3 and 4 carbon atoms ...