The Journal of Organic Chemistry

Syntheses and Diels-Alder reactions of two dimethyl 10-methoxyanthryl phosphates

JS Meek, LL Koh

文献索引：Meek,J.S.; Koh,L.L. Journal of Organic Chemistry, 1968 , vol. 33, p. 2942 - 2946

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被引用次数: 14

摘要

Dimethyl 10-methoxy-9-anthryl phosphate (3) and dimethyl 4, 5dichloro-lO-methoxy-9- anthryl phosphate (5) were synthesized by treating anthraquinone and l, &dichloroanthraquinone with trimethyl phosphite. The structure of 5 was shown by its conversion into 1, 8dichloro-9-anthrone on treatment with a hydriodic acetic acid mixture and by its formation of 4, 5dichloro-l0-methoxyanthrone in aqueous sodium hydroxide. ...