Tetrahedron letters

Synthesis of diols using the hypervalent iodine (III) reagent, phenyliodine (III) bis (trifluoroacetate)

M Çelik, C Alp, B Coşkun, MS Gültekin, M Balci

文献索引：Celik, Murat; Alp, Cemalettin; Coskun, Betuel; Gueltekin, M. Serdar; Balci, Metin Tetrahedron Letters, 2006 , vol. 47, # 22 p. 3659 - 3663

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被引用次数: 29

摘要

1, 2-and 1, 3-Bis (trifluoroacetoxy) alcohols are easily obtained from the one-pot reaction of alkenes with phenyliodine (III) bis (trifluoroacetate)(PIFA) in the absence of any additive or catalyst. The products were converted into the corresponding diols by ammonolysis. The use of bicyclic alkenes has shown that rearranged 1, 3-diacetoxy alcohols are mostly formed as the major products.