The relative rates of bromination of cyclohexane and cyclopentane with molecular bromine. Comparison of the reactions in solution and in vapor phase

…, TCS Ruo, H Takiguchi, A Guillaume

文献索引：Tanner, Dennis D.; Ruo, Tomoki C-S.; Takiguchi, Hideki; Guillaume, Andre Canadian Journal of Chemistry, 1981 , vol. 59, p. 1368 - 1374

全文：HTML全文

被引用次数: 5

摘要

The relative rates of transfer of the cyclopentyl radical with molecular bromine and hydrogen bromide (k 2'/k-1') and with hydrogen tribromide and hydrogen bromide (k 3'/k-1') have been determined. The relative transfer rates are compared with the analogous values previously reported for the reactions of cyclohexyl radicals (k 2/k-1 and k 3/k-1). Utilizing the values of k 2'/k-1 and k 2/k-1 the competitive vapor phase rates of bromine atom abstraction of ...