Journal of the American Chemical Society

The alkylation of mercaptans by means of sulfonic esters

H Gilman, NJ Beaber

文献索引：Gilman; Beaber Journal of the American Chemical Society, 1925 , vol. 47, p. 1451

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被引用次数: 10

摘要

In connection with studies involving the interaction of organic sulfur compounds and organomagnesium halides it was necessary to prepare a variety of sulfides. When the hydrogen of a mercapto (--SH) group is to be replaced by alkyl, two classes of compounds are generally used: alkyl halides and salts of alkyl sulfates. Sulfonic esters have been used to a decidedly limited extent in a replacement reaction of this type, despite the fact that ...