Synthesis of oxosulfonium salts by the oxidation of sulfonium salts

…, H Takeuchi, H Minato, M Kobayashi…

文献索引：Mori, Mitsuo; Takeuchi, Hiroyuki; Minato, Hiroshi; Kobayashi, Michio; Yoshida, Masato; et al. Phosphorus, Sulfur and Silicon and the Related Elements, 1990 , vol. 47, # 1 + 2 p. 157 - 164

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被引用次数: 11

摘要

Abstract A general synthetic method for oxosulfonium salts by oxidation of sulfonium salts with sodium perbenzoate (or sodium m-chloroperbenzoate was developed. In case of the oxidation of aryldimethylsulfonium salts, the corresponding oxosulfonium salts (1e-h) were obtained in 64–91% yields. Diphenymethylsulfonium and triphenylsulfonium salts were also oxidized with sodium perbenzoate to afford the corresponding oxosulfonium salts (1i and ...