Australian Journal of Chemistry

Chemistry of the Podocarpaceae. LXI. The rearrangement of aryl phosphates to ortho-hydroxyaryl phosphonates

RC Cambie, BD Palmer

文献索引：Cambie, Richard C.; Palmer, Brian D. Australian Journal of Chemistry, 1982 , vol. 35, # 4 p. 827 - 837

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被引用次数: 25

摘要

Abstract Treatment of methyl 12-(diethoxyphosphoryloxy) podocarpa-8, 11, 13-trien-19-oate (14) or its 13-bromo derivative (7) with butyllithium effects a rearrangement of the phosphate group to give methyl 13-diethoxyphosphoryl-12-hydroxypodocarpa-8, 11, 13-trien-19-oate