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Journal of the Chemical Society C: Organic

Organophosphorus intermediates. Part II. Reaction of tervalent phosphorus compounds with tetraphenylcyclopentadienone

MJ Gallagher, ID Jenkins

文献索引:Gallagher,M.J.; Jenkins,I.D. Journal of the Chemical Society [Section] C: Organic, 1969 , vol. , p. 2605 - 2614

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被引用次数: 11

摘要

Trimethyl phosphite reacts with tetraphenylcyclopentadienone to give dimethyl 5-methyl-2, 3, 4, 5-tetraphenylcyclopenta-1, 3-dienyl phosphate (8), dimethyl 3-methyl-2, 3, 4, 5- tetraphenylcyclopenta-1, 4-dienyl phosphate (11) and 1, 2, 3, 4-tetraphenylfulvene. The reaction proceeds by way of Arbuzov rearrangements of an interm