Nucleophilicities of selected ions in water at 195. degree. C

GA Reed, DR Dimmel, EW Malcolm

文献索引：Reed, Gregg A.; Dimmel, Donald R.; Malcolm, Earl W. Journal of Organic Chemistry, 1993 , vol. 58, # 23 p. 6372 - 6376

全文：HTML全文

被引用次数: 2

摘要

The reaction of a benzyl aryl ether (3) with selected ions was studied to determine relative nucleophilicities at 195" C in water. Nucleophilic displacement by the ions occurred at the benzyl carbon to liberate a phenolic group. The primary products of the displacement were independently synthesized and reacted in alkali to determine their stability. Hydrosulfide ion was 20 times more reactive than hydroxide ion with this substrate, while ...