A new synthetic route for 1, 2-diketo compounds using unexpected C–C bond cleavage by PCC

…, AA Momin, RL Gawade, VG Puranik, RS Kusurkar

文献索引：Bhosale, Shrikar M.; Momin, Aadil A.; Gawade, Rupesh L.; Puranik, Vedavati G.; Kusurkar, Radhika S. Tetrahedron Letters, 2012 , vol. 53, # 39 p. 5327 - 5330

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被引用次数: 4

摘要

PCC is a well-known oxidizing agent, for the conversion of alcohols to aldehydes and ketones with high efficiency. 9 Several rearrangements and useful conversions are mediated by PCC. 10 and 11 This makes PCC a versatile reagent in organic synthesis. We herein report a new method for the synthesis of 1,2-diketo compounds by PCC mediated unexpected C–C bond cleavage. ... In our earlier endeavor of a total synthesis of a natural product, there was a ...