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Study of an Unexpected Rearrangement of the α-Phenyl Pyrane Derivatives Prepared via Hetero-Diels− Alder Reaction of Acyclic Vinyl Allenes and Aldehydes

JM Ruiz, D Regás, MM Afonso…

文献索引:Yeager, Adam R.; Min, Geanna K.; Porco Jr., John A.; Schaus, Scott E. Organic Letters, 2006 , vol. 8, # 22 p. 5065 - 5068

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被引用次数: 7

摘要

... in the semicyclic ones, and the two remaining substituents on the diene (R 1 and R 2 ) would ... Et 2 O to the aldehyde in ethyl ether at 0 °C, after 15 min addition of ... a doubly activated oxygen−carbon bond breaks under Lewis acid catalysis, was described by Porco, Schaus, and ...