Catalytic hydrogenation of aromatic hydrocarbons. Stereochemical definition of the catalytic cycle for. eta. 3-C3H5Co (P (OCH3) 3) 3

JR Bleeke, EL Muetterties

文献索引：Bleeke, J. R.; Muetterties, E. L. Journal of the American Chemical Society, 1981 , vol. 103, # 3 p. 556 - 564

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被引用次数: 56

摘要

Abstract: The q3-C3HSCo (P (OCH3) 3) 3-catalyzed hydrogenations with D2 of a series of unsaturated organic molecules, including cyclohexenes, cyclohexadienes, and arenes, have been investigated. Complete cis stereoselectivity was observed in the addition of deuterium to the unsaturated ring systems. When alkyl-substituted arenes were reduced with D2, the hydrogen atoms in the alkyl chains underwent HD exchange as long as each ...