Bulletin of the Korean Chemical Society

Rate and product studies on the solvolyses of allyl chloroformate

HJ Koh, SJ Kang

文献索引：Koh, Han Joong; Kang, Suk Jin Bulletin of the Korean Chemical Society, 2012 , vol. 33, # 12 p. 4117 - 4121

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被引用次数: 6

摘要

Abstract The solvolysis rate constants of allyl chloroformate (, 3) in 30 different solvents are well correlated with the extended Grunwald-Winstein equation, using the solvent nucleophilicity scale and solvent ionizing scale, with the sensitivity values of and for l and m, respectively. These l and m values can be considered to support a reaction pathway. The activation enthalpies () were 12.5 to 13.4 and the activation entropies () were-34.4 to-37.3, ...