Acyl iodides in organic synthesis: IX. Cleavage of the Si-OC and Si-O-Si moieties

…, AA Trukhina, LI Belousova, GA Kuznetsova…

文献索引：Voronkov; Trukhina; Belousova; Kuznetsova; Vlasova Russian Journal of Organic Chemistry, 2007 , vol. 43, # 4 p. 501 - 506

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被引用次数: 11

摘要

Abstract Reactions of acyl iodides RCOI (R= Me, Ph) with organosilicon compounds involve cleavage of the Si-OC and Si-O-Si fragments. Acetyl iodide reacts with alkyl (alkoxy) silanes with evolution of heat, and cleavage of the Si-O bond results in the formation of oligo-or polysiloxanes, alkyl iodides, and alkyl acetates. 1, 3-Diacetoxytetramethyldisiloxane is formed in the reaction of acetyl iodide with dimethoxy (dimethyl) silane. Acyl iodides ...