First Report for the Efficient Reduction of Oximes to Amines with Zinc Borohydride in the form of (Pyridine)(tetrahydroborato) zinc Complex

B Zeynizadeh, K Zahmatkesh

文献索引：Zeynizadeh, Behzad; Zahmatkesh, Karam Journal of the Chinese Chemical Society, 2005 , vol. 52, # 1 p. 109 - 112

全文：HTML全文

被引用次数: 15

摘要

(Pyridine)(tetrahydroborato)zinc complex, (Py)Zn(BH4)2, as a stable modification of zinc borohydride can easily reduce a variety of aromatic and aliphatic aldoximes or ketoximes to their corresponding amines in high to excellent yields in refluxing THF. ... Keywords: Zinc borohydride; Tetrahydroborate; Reduction; Oxime; Amine. ... Today's reduction with metal borohydrides is one of the most widely used procedures in organic synthesis. To achieve reductants with ...