Alkylation and acylation of the iron carbonyl anion [(CO) 4FeSi (CH3) 3]-. Evidence for 1, 3-silatropic shifts from iron to acyl oxygen

…, AJ Blakeney, W Krone-Schmidt, JA Gladysz

文献索引：Brinkman, Kerry C.; Blakeney, Andrew J.; Krone-Schmidt, Wilfried; Gladysz, J. A. Organometallics, 1984 , vol. 3, p. 1325 - 1332

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被引用次数: 38

摘要

Metal carbonyl anions are generally strong nucleophiles that undergo ready alkylation and acylati~ n.~ Hence they are valuable precursors to complexes with metal-carbon u bonds. Functionalized metal carbonyl anions (eg,(CO), MX-) offer an extra dimension of reactivity in that subsequent transformations can follow metal-carbon u bond formation. For instance, Collman has utilized the reagent [Fe (C0), l2-to effect a number of useful organic ...