Capturing a Ghost. Synthesis and Structural Characterization of Pd (dba)[P (o-Tol) 3] 2

…, W Dougherty Jr, S Kassel, FE Goodson

文献索引：Harding, Brennen A.; Melvin, Patrick R.; Dougherty, William; Kassel, Scott; Goodson, Felix E. Organometallics, 2013 , vol. 32, # 12 p. 3570 - 3573

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被引用次数: 8

摘要

In an effort to improve upon a literature synthesis of bis [tris (o-tolyl) phosphine] palladium (0)(1) from tris (o-tolyl) phosphine and Pd2 (dba) 3, we instead isolated a new compound which proved to have the composition Pd (dba)[P (o-Tol) 3] 2 (2), upon analysis by X-ray crystallography. While this is not the first known palladium compound containing both dba and phosphine ligands, it is, to our knowledge, the first containing dba and tris (o-tolyl) ...