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The Journal of Organic Chemistry

Reactions of 3-methylbenzyne with 2-substituted furans. Steric effects

MS Newman, R Kannan

文献索引:Newman,M.S.; Kannan,R. Journal of Organic Chemistry, 1976 , vol. 41, # 21 p. 3356 - 3359

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被引用次数: 41

摘要

3-Methylbenzyne generated from two pairs of isomeric precursors, namely, 2-amino-3- methylbenzoic acid (1)-2-amino-6-methylbenzoic acid (2) and 2-fluoro-3- methylbromobenzene (3)-6-fluoro-2-methylbromobenzene (4), has been reacted with 2- methylfuran (5), 2-tert-butylfuran (6), 2-(1, 3-dioxolan-2-yl) furan (7), and 2- carbomethoxyfuran (8). The proportions of isomeric adducts produced were the same (&2 ...