Canadian Journal of Chemistry

Formation and reactions of (1-chloroalkyl) carbamoyl chlorides. Synthesis of 1, 2, 4-triazolidine-5-ones

K Koyano, CR McArthur

文献索引：Koyano,K.; McArthur,C.R. Canadian Journal of Chemistry, 1973 , vol. 51, p. 333 - 337

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被引用次数: 5

摘要

N-(α-Chlorobenzyl) carbaniloyl chloride and (α-chlorobenzyl) methylcarbamoyl chloride are formed by reaction of phosgene with N-benzylideneaniline and N-benzylidenemethylamine, respectively. Reaction of these carbamoyl chlorides with a number of nucleophiles is described, some of which cause cleavage of the benzyl to nitrogen bond while others give rise to substitution products without such cleavage. Of the latter type, substituted ...