Structures of organic cations in the gas phase. Neutral products from fluoride abstraction examined by NMR

EW Redman, KK Johri, TH Morton

文献索引：Redman, Eric W.; Johri, Kamalesh K.; Morton, Thomas Hellman Journal of the American Chemical Society, 1985 , vol. 107, p. 780 - 784

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被引用次数: 14

摘要

Abstract: Structures of 2-fluoroisopropyl cation (1) and 2-propenyl cation (2) in the gas phase have been examined by quenching via ion-molecule reactions and examination of the neutral products by NMR. Both ions are produced by 70-eV electron bombardment of fer?- butyl fluoride, and both react with the parent neutral to yield tert-butyl cation. The ion- molecule reaction of 1 yields 2, 2-difluoropropane as> 90% of the neutral product. The ion ...