Polyhedron

Use of pyrazolyl ligands for the formation of a bimetallic cobalt–ruthenium complex

Y Shi, AM Arif, RD Ernst

文献索引：Shi, Yifan; Arif, Atta M.; Ernst, Richard D. Polyhedron, 2011 , vol. 30, # 11 p. 1899 - 1905

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被引用次数: 1

摘要

Abstract A straightforward route to Ru (pyz) 2 (Hpyz) 4 (Hpyz= pyrazole) has been developed. This has been found to react readily with a modified Co (pyrazolylborate) Cl complex in the presence of triethylamine as an HCl acceptor to yield a bimetallic cobalt– ruthenium complex, in which the two metals are each six-coordinate, and bridged by three pyrazolyl anions. Both species have been characterized structurally, as has a modified Co ...