[CF2Cl-], Chlorodifluoromethide ion. Capture of an elusive species

DJ Burton, GA Wheaton

文献索引：Burton,D.J.; Wheaton,G.A. Journal of the American Chemical Society, 1974 , vol. 96, p. 6787 - 6788

全文：HTML全文

被引用次数: 20

摘要

The concerted nature of difluorocarbene formation via the decomposition of chlorodifluoroacetic acid and its derivatives is presently accepted as there is no concrete evidence for the existence of the chlorodifluoromethide ion in the literature to date. Herein is reported evidence supporting the existence of the chlorodifluoromethide ion as a reactive intermediate in the decarboxylation of methyl chlorodifluoroacetate. Independent ...