Sulfides as precursors for sulfonyl chloride synthesis

RF Langler, ZA Marini…

文献索引：Langler,R.F. et al. Canadian Journal of Chemistry, 1979 , vol. 57, p. 3193 - 3199

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被引用次数: 16

摘要

Sulfides are advanced as sulfonyl chloride precursors. SN2 cleavage of the intermediate sulfonium ions is discussed in conjunction with both the sulfohaloform pathway and our previous hypothesis that asymmetric chlorosulfonium chloride salts undergo Pummerer rearrangements which exhibit regioselectivity that can be anticipated on the basis of substituent electronegativity difference (Δ X p). Thioglycolic acid is developed as a new ...