A One-Pot Azido Reductive Tandem Mono-N-Alkylation Employing Dialkylboron Triflates: Online ESI-MS Mechanistic Investigation

…, V Srinivasulu, K Sreekanth, CS Reddy…

文献索引：Shankaraiah, Nagula; Markandeya, Nagula; Srinivasulu, Vunnam; Sreekanth, Kokkonda; Reddy, Ch. Sanjeeva; Santos, Leonardo S.; Kamal, Ahmed Journal of Organic Chemistry, 2011 , vol. 76, # 17 p. 7017 - 7026

全文：HTML全文

被引用次数: 13

摘要

An efficient one-pot reductive tandem mono-N-alkylation of both aromatic and aliphatic azides using dialkylboron triflates as alkylating agents has been examined under standardized reaction conditions. This methodology after optimization has been employed toward the syntheses of various secondary alkyl as well as aryl amines, including the synthesis of N10-butylated pyrrolo [2, 1-c][1, 4] benzodiazepine-5, 11-diones via in situ ...