Chemistry of diarylazoalkanes. III. Effect of structural variation on rate and nature of the thermal decomposition

P Kovacic, RR Flynn, JF Gormish…

文献索引：Kovacic,P. et al. Journal of Organic Chemistry, 1969 , vol. 34, p. 3312 - 3315

被引用次数: 25

摘要

Results The azo compounds [p, p'-difluoro-, p, p'-dichloro-, and m, m'-dichloroazocumenes and l, l'-di (4-tolyl) azocyclohexane] were prepared by oxidation of the corresponding amines with iodine pentafluoride according to a modificatione of the procedure of Nelsen and Bartlett. 6 The yields and physical properties are listed in Table I. Rates of decomposition were obtained by following the disappearance in the ultraviolet (uv) ...