Reaction of hydrogen atoms with diethylsulfide

MM Ekwenchi, I Safarik…

文献索引：Ekwenchi, Mbanefo Mbonu; Safarik, Imre; Strausz, Otto Peter Canadian Journal of Chemistry, 1981 , vol. 59, p. 3226 - 3231

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被引用次数: 8

摘要

In the reactions of H atoms, generated by the Hg (3 P 1)-sensitized decomposition of H2, with C2H5SC2H5 the primary reaction has been established to be with k 1=(4.7±0.9)× 1013 exp [-(3797±152)/RT] cm3 mol-1 sl relative to the rate constant of the H+ C2H4→ C2H5 reaction. The mechanism postulated explains adequately all the experimental observations. The entropy of activation for the primary reaction,-22.1 eu is close to the value obtained for ...