Free-radical chain addition reactions of aldehydes with perfluoro ketones and chloro perfluoro ketones

WH Urry, A Nishihara, JHY Niu

文献索引：Urry,W.H. et al. Journal of Organic Chemistry, 1967 , vol. 32, p. 347 - 352

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被引用次数: 36

摘要

The yields given are based upon ketone consumed. Conversions (with Ia: 50%; Ib, 91%; IC, 75%; and Id, 12%) differed, and with Id a product of dehydrochlorination of IId (20%) was also obtained. With alkanals I11 and 111', this reaction gives the analogous esters IVa-, d and IV'a-d as well as the ter-