Amines made easily: a highly selective hydroaminomethylation of olefins

M Ahmed, AM Seayad, R Jackstell…

文献索引：Ahmed, Moballigh; Seayad, Abdul Majeed; Jackstell, Ralf; Beller, Matthias Journal of the American Chemical Society, 2003 , vol. 125, # 34 p. 10311 - 10318

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被引用次数: 166

摘要

A highly chemo-and regioselective hydroaminomethylation of simple as well as functionalized α-olefins using a cationic rhodium precatalyst together with Xantphos as ligand is reported. Studies of the influence of ligands and reaction conditions led to an unprecedented selective hydroaminomethylation procedure. The novel procedure constitutes an economically attractive and environmentally favorable synthesis of ...