An Efficient Solvent??Free Route to Silyl Esters and Silyl Ethers

Y Ojima, K Yamaguchi, N Mizuno

文献索引：Ojima, Yuko; Yamaguchi, Kazuya; Mizuno, Noritaka Advanced Synthesis and Catalysis, 2009 , vol. 351, # 9 p. 1405 - 1411

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被引用次数: 32

摘要

Abstract: Dinuclear metal complexes, especially (pcymene) ruthenium dichloride dimer {[ RuCl2ACHTUNGTRENNUNG (pcymene)] 2}, have been found to exhibit high catalytic performance for the dehydrosilylation of various kinds of carboxylic acids and alcohols. The dehydrosilylation with [RuCl2ACHTUNGTRENNUNG (p-cymene)] 2 proceeded efficiently with only one equivalent of silane with respect to substrate (carboxylic acids or alcohols) ...