European Journal of Inorganic Chemistry

[Bis (oxazolinyl) pyrrole] palladium Complexes as Catalysts in Heck??and Suzuki??Type C− C Coupling Reactions

C Mazet, LH Gade

文献索引：Mazet, Clement; Gade, Lutz H. European Journal of Inorganic Chemistry, 2003 , # 6 p. 1161 - 1168

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被引用次数: 17

摘要

Abstract The two bis (oxazoline) pyrrole ligand precursors 2, 5-bis (4, 4′-dimethyl-4, 5- dihydrooxazol-2-yl) pyrrole (“dmoxpH”, 2) and 2, 5-bis (4, 4′-dimethyl-4, 5-dihydrooxazol-2- yl)-3, 4-diethylpyrrole (“Et 2 dmoxpH”, 5) have been synthesised and metallated by treatment with n-butyllithium at− 78 C in diethyl ether. Treatment of the lithium pyrrolide with 1.1 mol- equiv. of [PdCl 2 (COD)] gave the corresponding helical dinuclear palladium complexes [ ...