Tetrahedron

The reaction of lead tetraacetate with alicyclic alcohols—I cycloalkanols

ML Mihailovič, Ž Čeković, V Andrejević, R Matić…

文献索引：Mihailovic,M.L. et al. Tetrahedron, 1968 , vol. 24, p. 4947 - 4961

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被引用次数: 4

摘要

Secondary cycloalkanols, containing 4-to 16-membered rings, have been treated with lead tetraacetate in refluxing benzene. It was found that the ease of oxidation to the corresponding ketones follows the reactivity order of reactions of alicyclic compounds involving an sp3→ sp2 ring carbon hybridization change, and that the amount of β- fragmentation resulting in opening of the ring is in accord with the total strain associated ...