The Journal of Organic Chemistry

New desulfurizations by nickel-containing complex reducing agents

S Becker, Y Fort, P Caubere

文献索引：Becker, Sandrine; Fort, Yves; Caubere, Paul Journal of Organic Chemistry, 1990 , vol. 55, # 25 p. 6194 - 6198

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被引用次数: 40

摘要

Desulfurizations of saturated aliphatic or aromatic sulfoxides or sulfones are efficiently performed with nickel complex reducing agents (NiCRA's). The complete desulfurization of dithioketals can be effected in high yields with these reagents, while their half- desulfurization is efficiently achieved with 2, 2'-bipyridine-modified nickel complex reducing agents (NiCRA-bpy). The desulfurization of vinyl thioethers, sulfoxides, and sulfones have ...