Synthetic studies toward sordarin: building blocks for the terpenoid core and for analogues thereof

…, H Liang, JP Vors, MA Ciufolini

文献索引：Schule, Arnaud; Liang, Huan; Vors, Jean-Pierre; Ciufolini, Marco A. Journal of Organic Chemistry, 2009 , vol. 74, # 4 p. 1587 - 1597

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被引用次数: 13

摘要

Avenues to bi-and tricyclic building blocks for the elaboration of sordaricin and its analogues are described. The target molecules were obtained through inter-and intramolecular Diels− Alder reactions of a number of previously unknown cyclopentadienes. Unusual properties of 3-cyanoenones and 1-cyanocyclopentadienes have been unveiled and circumvented.