Indium Triiodide Catalyzed Direct Hydroallylation of Esters

…, Y Inamoto, T Saito, M Yasuda, A Baba

文献索引：Nishimoto, Yoshihiro; Inamoto, Yoshihiro; Saito, Takahiro; Yasuda, Makoto; Baba, Akio European Journal of Organic Chemistry, 2010 , # 18 p. 3382 - 3386

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被引用次数: 6

摘要

Abstract The InI 3-catalyzed hydroallylation of esters by using hydro-and allysilanes under mild conditions has been accomplished. Many significant groups such as alkenyl, alkynyl, cyano, and nitro ones survive under these conditions. This reaction system provided routes to both homoallylic alcohols and ethers, in which either elimination of the alkoxy moiety or of the carbonyl oxygen atom could be freely selected by changing the substituents on the ...