Chemistry Letters

Switching reaction pathways of benzo [b] thiophen-3-yllithium and benzo [b] furan-3-yllithium based on high-resolution residence-time and temperature control in a …

…, A Takata, Y Ushiogi, Y Iinuma, A Nagaki, J Yoshida

文献索引：Asai, Tatsuro; Takata, Atsushi; Ushiogi, Yousuke; Iinuma, Yoshiharu; Nagaki, Aiichiro; Yoshida, Jun-Ichi Chemistry Letters, 2011 , vol. 40, # 4 p. 393 - 395

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被引用次数: 13

摘要

Reaction-pathway control of benzo [b] thiophen-3-yllithium and benzo [b] furan-3-yllithium was accomplished in flow microreactor systems. We could switch between the reaction with an electrophile before ring-opening and that after ring-opening at will by choosing an appropriate residence-time and temperature.