Tetrahedron

A convenient synthesis of olefins via deacylation reaction

S Nakatsu, AT Gubaidullin, VA Mamedov, S Tsuboi

文献索引：Nakatsu, Shogo; Gubaidullin, Aider T.; Mamedov, Vakhid A.; Tsuboi, Sadao Tetrahedron, 2004 , vol. 60, # 10 p. 2337 - 2349

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被引用次数: 17

摘要

A convenient and environmentally-friendly synthetic method of olefins via deacylation reaction is described. The reaction gives olefins by condensation of aldehydes with a variety of 1, 3-dicarbonyl compounds in the presence of anhydrous potassium carbonate at room temperature in high yields (70–90%) in one step. The synthetic potential of this strategy can be used as an alternative procedure to the Wittig, Wittig–Horner reactions. The ...