Journal of organometallic chemistry

Probing delocalisation across highly ethynylated mono and dinuclear Pt (II) tethers containing nitrogroups and organic models as redox active probes: X-ray crystal …

M Ravera, R D'Amato, A Guerri

文献索引：Ravera, Mauro; D'Amato, Rosaria; Guerri, Annalisa Journal of Organometallic Chemistry, 2005 , vol. 690, # 9 p. 2376 - 2380

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被引用次数: 16

摘要

The electrochemical study on Pt (II) organometallic and organic ethynylated compounds bearing nitro substituents in the phenyl groups has been performed, demonstrating that the presence of severe chemical irreversibility accompanying the electron transfer, preclude an evaluation of the electronic communication between redox active centres. The X-ray structure of the complex trans-[Pt (CC–C6H4NO2) 2 (PPh3) 2] is showed.