Homogeneous catalytic system for reversible dehydrogenation− hydrogenation reactions of nitrogen heterocycles with reversible interconversion of catalytic species

R Yamaguchi, C Ikeda, Y Takahashi…

文献索引：Yamaguchi, Ryohei; Ikeda, Chikako; Takahashi, Yoshinori; Fujita, Ken-Ichi Journal of the American Chemical Society, 2009 , vol. 131, p. 8410 - 8412

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被引用次数: 126

摘要

The first homogeneous catalytic system for the efficient reversible dehydrogenation− hydrogenation reactions of nitrogen heterocycles in one flask has been developed using the pyridonate Cp* Ir complex as the single catalyst at relatively low temperature. The reversible catalytic reactions proceed with the reversible interconversion of catalytic species and can be nearly quantitatively repeated five times with almost no loss of efficiency. The ...